Question
Although these analyzers were invented in the 1940s, they were worthless until soft ionization techniques like MALDI (“MAWL-dee”) became popular in the 2000s. For 10 points each:
[10m] Name these mass analyzers that excite all fragment ions to the same kinetic energy and then measure their velocities over a fixed linear distance.
ANSWER: time-of-flight mass analyzers [or TOF mass spectrometry]
[10e] For every fragmented ion, the measured time-of-flight is used to compute the ratio of the ion’s mass to this quantity.
ANSWER: charge [accept mass-to-charge ratio or m-over-z]
[10h] TOF (“toff”) analyzers are also used by materials scientists as detectors for this technique. This technique uses a charged microscope tip to ionize a surface and detect its molecular composition with excellent spatial resolution.
ANSWER: atom probe tomography [or APT; prompt on tomography]
Data
| Team | Opponent | Part 1 | Part 2 | Part 3 | Total |
|---|---|---|---|---|---|
| Brown A | Duke A | 10 | 10 | 0 | 20 |
| Chicago C | Cornell B | 0 | 10 | 0 | 10 |
| Columbia B | Houston A | 10 | 10 | 0 | 20 |
| Cornell A | Chicago A | 10 | 10 | 0 | 20 |
| Florida B | Minnesota B | 10 | 10 | 0 | 20 |
| Georgia Tech A | Ohio State A | 10 | 10 | 0 | 20 |
| Georgia Tech B | Penn State A | 0 | 10 | 0 | 10 |
| Harvard A | UC Berkeley A | 10 | 10 | 0 | 20 |
| Illinois A | WUSTL B | 0 | 0 | 0 | 0 |
| Imperial A | Vanderbilt A | 0 | 10 | 0 | 10 |
| Johns Hopkins A | Rutgers B | 0 | 10 | 0 | 10 |
| MIT A | Columbia A | 10 | 10 | 0 | 20 |
| Maryland A | Florida A | 0 | 10 | 0 | 10 |
| McGill A | Virginia A | 0 | 10 | 0 | 10 |
| Michigan A | UC Berkeley B | 0 | 10 | 0 | 10 |
| Minnesota A | Indiana A | 10 | 10 | 0 | 20 |
| North Carolina A | Texas A | 10 | 10 | 0 | 20 |
| Northwestern A | Toronto A | 10 | 10 | 0 | 20 |
| Penn A | South Carolina A | 0 | 10 | 0 | 10 |
| Purdue A | NYU A | 10 | 10 | 0 | 20 |
| Rutgers A | Iowa State A | 10 | 10 | 0 | 20 |
| Stanford A | WUSTL A | 10 | 10 | 0 | 20 |
| Yale A | Chicago B | 10 | 10 | 0 | 20 |
| Yale B | Claremont A | 0 | 10 | 0 | 10 |